期刊
CHEMICAL SOCIETY REVIEWS
卷 31, 期 5, 页码 247-258出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b006015l
关键词
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Aziridines, the nitrogenous analogues of epoxides, have until recently excited far less interest amongst synthetic organic chemists than their oxygenated counterparts, with some justification. A range of reviews concerned with the physical properties,(1) synthesis (asymmetric(2) and otherwise(3)), reactions(4) and utility of aziridines exists; this review briefly summarizes the similarities and differences between oxiranes and their nitrogenated analogues, concentrating on the underlying properties of aziridines and recent developments in their chemistry. In addition to descriptions of the physical nature of aziridines, especially those features which underpin their utility as synthetic intermediates, the sections beneath describe reactions involving alkylative ring-opening and synthesis of aziridines.
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