期刊
JOURNAL OF CHROMATOGRAPHY A
卷 969, 期 1-2, 页码 97-101出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0021-9673(02)00370-9
关键词
thermodynamic parameters; inverse gas chromatography; adsorption; lipophilicity; sucrose; phospholipids; lipids; polyglycerol polyricinoleate
Inverse gas chromatography (IGC) was employed to characterize the changes in surface properties of sucrose particles coated with either lecithin or polyglycerol polyricinoleate. IGC was performed using polar and non-polar adsorbates at infinite dilution with the sucrose particles as the solid stationary phase. Coating the sugar surface with emulsifiers induced an increase in the lipophilicity of the sugar particles, i.e. a sharp decrease in the acidity of the surface. Yet the two emulsifiers induced a slightly different increase in the surface basicity. It was hypothesized that this observation was due to a difference in the molecular structure of the emulsifiers. (C) 2002 Elsevier Science B.V. All rights reserved.
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