期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 67, 期 18, 页码 6546-6549出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0258204
关键词
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A novel alkaloid with an unprecedented fused-hexacyclic skeleton, daphmanidin A (1), and a new pentacyclic alkaloid, daphmanidin B (2), have been isolated from the leaves of Daphniphyllum teijsmanii, and the structures were elucidated on the basis of spectroscopic data. The relative and absolute stereochemistry of 1 was determined by combination of NOESY correlations and a modified Mosher method.
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