期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 533, 期 1-2, 页码 177-180出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(02)01073-2
关键词
conductive diamond; europium; electron transfer; outer-sphere redox couple; cyclic voltammetry
In the present paper, the electrochemical behavior of the Eu(III)/Eu(II) redox couple has been investigated at conductive diamond thin film electrodes. Measurements have been carried out by means of cyclic voltammetry, quasi-steady polarization curves (low-overpotential approximation) and ac impedance. The experimental picture indicates that the kinetics of electron transfer are more complex than that suggested by a classical outer-sphere mechanism. (C) 2002 Elsevier Science B.V. All rights reserved.
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