期刊
TETRAHEDRON LETTERS
卷 43, 期 39, 页码 6903-6905出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)01623-4
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The main product of the horseradish peroxidase-mediated oxidative coupling of 3-methylindole by H2O2 has been found to be the same compound previously obtained from chemical, radiolytic, and anodic oxidation of 3-methylindole and claimed to be a hexahydrofurodiindole of undefined stereochemistry (meso versus d,l). Single-crystal X-ray diffraction analysis of the Compound, aimed at determining the stereochemistry, revealed that the actual product is an isomer, 7,8-dimethyl-2-oxa-4,11-diazadibenzo[e,i]tricyclo[5.4.0.0(3,8)]undecane that derives from hydrolytic reorganization of the initially formed biindoline radical coupling product. (C) 2002 Published by Elsevier Science Ltd.
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