期刊
CHIRALITY
卷 14, 期 9, 页码 724-726出版社
WILEY-LISS
DOI: 10.1002/chir.10131
关键词
azo compounds; binaphthyl; palladium; phosphines; photoisomerization
Novel photoresponsive axially chiral monophosphine ligands containing azobenzene moiety were prepared and applied to a palladium-catalyzed allylic alkylation. The reaction of rac-1,3-diphenyl-2-propenyl acetate gave the alkylated products with up to 90% enantiomeric excess. The ligand exhibited a trans to cis photoisomerization upon irradiation with UV light. (C) 2002 Wiley-Liss,lnc.
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