期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 67, 期 21, 页码 7565-7568出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo025988p
关键词
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The synthesis of a sialic acid dimer derivative, Neu5Acalpha(2-->5)Neu5Gc, is described. The synthetic strategy is based on the use of allyl alcohol to achieve an exclusive alpha-sialylation product. The allyloxy group is also a latent glycolic acid that provides the subsequent coupling with neuraminate with minimal protection-deprotection manipulations.
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