期刊
JOURNAL OF PHYSICS-CONDENSED MATTER
卷 14, 期 42, 页码 9955-9973出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/14/42/309
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Achieving exquisite control of the structural organization in molecular arrangements of pi-conjugated (macro)molecules with tailored chemical functionalities and physical properties is an essential prerequisite for the reproducible fabrication of high-performance molecular electronic devices. This paper reports on the exploitation of scanning probe microscopies to investigate pi-conjugated oligomeric and polymeric architectures assembled on flat solid substrates. These techniques provide genuine insight into the structure of the molecular arrangements as well as into their physicochemical properties over a wide range of length scales. Moreover, they allow one to manipulate organic adsorbates with a precision on the molecular scale, opening a pathway towards the nanopatterning of surfaces and the development of single-molecule devices.
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