期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 40, 期 21, 页码 3711-3724出版社
JOHN WILEY & SONS INC
DOI: 10.1002/pola.10449
关键词
polyamides; step-growth polymerization; thermal properties; structure-property relations; quantum mechanical calculations
A series of polyisophthalamides containing pendent phthalimido groups and flexible side spacers were prepared from four novel diacids and three commercial aromatic diamines. These polyamides were prepared in high yields and with high molecular weights by direct polycondensation with triphenyl phosphite and pyridine as condensing agents. The weight-average and number-average molecular weights, measured by gel permeation chromatography, were 70,000-137,000 and 47,000-86,000 g/mol, respectively. The novel polyamides were amorphous and readily soluble and showed glass-transition temperatures of 150-240 degreesC, as measured by differential scanning calorimetry. Thermogravimetric analysis showed that the 10% weight-loss temperatures in nitrogen were 355-430 degreesC, a significant improvement in thermal stability having been observed with the increase in the side-chain length. A theoretical quantum mechanical study was successfully carried out to explain these results. Flexible and tough films, cast from polymer solutions, showed tensile strengths of 50-125 MPa. (C) 2002 Wiley Periodicals, Inc.
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