期刊
JOURNAL OF PHYSICS-CONDENSED MATTER
卷 14, 期 43, 页码 10159-10171出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/14/43/313
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High resolution neutron powder diffraction and single crystal measurements on the ferromagnetic shape memory compound Ni2MnGa have been carried out. They enabled the sequence of transformations which take place when the unstressed, stoichiometric compound is cooled from 400 to 20 K to be established. For the first time the crystallographic structure of each of the phases which occur has been determined. At 400 K the compound has the cubic L2(1) structure, and orders ferromagnetically at Tc approximate to 365 K. On cooling below similar to260 K a super-structure, characterized by tripling of the repeat in one of the <110> cubic directions, forms. This phase, known as the pre-martensitic phase, persists down to the structural phase transition at T-M approximate to 200 K and can be described by an orthorhombic unit cell with lattice parameters a(ortho) = 1/root2a(cubic), b(ortho) = 3/root2a(cubic), c(ortho) = a(cubic) and space group Pnnm. Below T-M the compound has a related orthorhombic super-cell with b(ortho) approximate to 7/root2a(cubic), which can be described within the same space group. The new modulation appears abruptly at T-M and remains stable down to at least 20 K.
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