期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 106, 期 46, 页码 11127-11129出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp021478n
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Experimental kinetic data related to the reaction of carbonyl compounds with peroxynitrite anion, ONOO-, in aqueous solutions was combined with estimated rate constants for the recombination of alkoxyl radicals with nitrogen dioxide. The equilibrium constants for O- transfer from ONOO- and OH transfer from ONOOH to the carbonyls were derived and the Gibbs' energies of formation of the neutral and anionic alpha-hydroxy alkoxyl radicals were calculated. By means of these data the O-H bond strengths in carbonyl hydrates as well as reduction potentials of the alkoxyl radicals were obtained.
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