期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 22, 页码 2718-2719出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b206811g
关键词
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Steric hindrance to solvation disfavors structures like 1 synanti in which the melamine exposes to the solvent faces, such as tBu-H, for whom binding to the ring nitrogen is hindered but not blocked; steric hindrance to solvation lowers the barriers to rotation in solvents which bind the triazine nitrogens, therefore these solvents display the fastest rates for assembling/disassembling processes.
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