期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 106, 期 47, 页码 12158-12164出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp0203189
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Rectification was observed across a monolayer of 2,6-di [dibutylamino-phenylvinyl]- 1-butylpyridinium iodide, (Bu(2)NphiV)(2)BuPy+I-, 1 sandwiched between gold electrodes. The current is enhanced at a forward bias above 0.5 to 1.0 V, as electrons flow preferentially from the iodide ions to the pyridinium ring, and is as high as 100 000 electrons molecule(-1) s(-1), with a rectification ratio of up to 90.
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