C2 and C3 hydrocarbon separations in poly(1,5-naphthalene-2,2′-bis(3,4-phthalic) hexafluoropropane) diimide (6FDA-1,5-NDA) dense membranes

The transport of olefin and paraffin namely ethane, ethylene, propane and propylene in aromatic poly(1,5-naphthalene2,2'-bis(3,4-phthalic) hexafluoropropane) diimide (6FDA-1,5-NDA) dense membranes was investigated. The gas permeability coefficients were measured at pressures from 2.5 to 16 atm for the C-2 hydrocarbon gases and pressures up to 8.4 atm for C-3 systems at 35 degreesC. This membrane exhibits permeabilities of 0.15, 0.87, 0.023 and 0.24 Barrer with respect to pure ethane, ethylene, propane and propylene, and shows an ideal selectivity of 5.8 for the separation of ethylene/ethane, 10 for propylene/propane, 7.6 for nitrogen/ethane and 50 for nitrogen/propane. The olefins showed a preferred permeability to paraffins and discussion were drawn to the permeability, diffusivity and solubility coefficients. The activation energies of permeation, diffusion and solution were also reported and the effect of temperature on the permeation properties was discussed for the pure gas permeability data obtained from 30 to 50 degreesC. The plasticisation effect was also found for propane and propylene, respectively, although it was neither detected in the saturated nor unsaturated C-2 hydrocarbons at pressures up to 16 atm. (C) 2002 Elsevier Science B.V. All rights reserved.