期刊
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
卷 15, 期 12, 页码 790-795出版社
JOHN WILEY & SONS LTD
DOI: 10.1002/poc.543
关键词
binary solvent mixtures; NMR spectroscopy; NOESY; preferential solvation
The solvation of some neutral and charged organic molecules (phenol, nitroanilines, tetraalkylammonium) in binary solvent mixtures was investigated by means of intermolecular H-1-NOESY NMR spectroscopy. The solvation shell of the solute is, in most cases, selectively enriched in one of the cosolvents (preferential solvation). The origin of preferential solvation is discussed in terms of solute-solvent interactions and microheterogeneity in the solvent mixture. Copyright (C) 2002 John Wiley Sons, Ltd.
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