Triterpene glycosides from the deep-water North-Pacific sea cucumber Synallactes nozawai Mitsukuri

Five non-sulfated triterpene glycosides, synallactosides A(1) (1), A(2) (2), B-1 (3), B-2 (4), and C (5), have been isolated from the sea cucumber Synallactes nozawai. Their structures have been deduced by extensive analysis of NMR and mass spectra. The glycosides 2-5 are new glycosides. Glycosides 2-4 have carbohydrate chains without precedent in the glycosides from sea cucumbers. This is the first time glycosides are found in members of the family Synallactidae.