期刊
CURRENT OPINION IN CHEMICAL BIOLOGY
卷 6, 期 6, 页码 779-785出版社
ELSEVIER SCI LTD
DOI: 10.1016/S1367-5931(02)00383-6
关键词
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The mechanism of thionitrite decomposition, both in vivo and in vitro, remains unclear. Thionitrite stability is highly variable; it is a complex function of thionitrite structure and environmental condition. Several recent advances clarify the role of unimolecular homlytic decomposition, metal-catalyzed reductive decomposition and higher-order enzymatic and non-enzymatic processes to the overall observed stability of thionitrites.
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