期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 75, 期 12, 页码 2687-2690出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.75.2687
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Treatment of terminal acetylenes with butyllithium, followed by an addition of gallium trichloride, afforded the corresponding alkynylgallium reagents. The reaction of the resulting alkynylgallium with alpha-halo carbonyl compounds in the presence of triethylborane as a radical initiator provided beta,gamma-acetylenic carbonyl compounds in good yields.
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