期刊
TETRAHEDRON LETTERS
卷 43, 期 49, 页码 8819-8822出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02235-9
关键词
chemoselectivity; glycosylation; novel synthetic strategy; glycosyl donors
Novel semi-orthogonal glycosylation strategy with the use of 0-pentenyl and thioglycosides has been developed. According to this technique both armed and disarmed thioglycosides can be selectively activated with MeOTf in the presence of either armed or disarmed 0-pentenyl glycosides. The applicability of this novel strategy for the synthesis of a trans-cis glycosylation pattern, not accessible via conventional armed-disarmed approach, has been demonstrated for the synthesis of a linear tetrasaccharide derivative. (C) 2002 Elsevier Science Ltd. All rights reserved.
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