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卷 43, 期 51, 页码 9405-9409出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02331-6
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The squaric acid-catalyzed imino-Diels-Alder reaction of enamine 4 with the imine 5 provides the pyrroloquinolines 6 and 7, which were converted to the triamine 3 using regioselective reduction and a Wittig reaction as the key steps. Guanylation of 3 followed by coupling with the alcohol 19 furnished the total synthesis of (+/-)-martinelline. (C) 2002 Elsevier Science Ltd. All rights reserved.
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