期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 23, 期 17, 页码 1049-1054出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200290002
关键词
MADIX; MALDI; molecular weight distribution/molar mass distribution; radical polymerization; xanthates
The capability of three chain-transfer agents, O-alkyl-S-(1-ethoxycarbonyl)ethyl xanthates (CH3-CHCO2C2H5)S(C=S)OZ', to control the free-radical polymerization of styrene and ethyl acrylate by the MADIX process was examined. The reactivity of the xanthates varied according to the following trend: Z'=CH2CH3
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