期刊
TETRAHEDRON LETTERS
卷 43, 期 52, 页码 9489-9492出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02452-8
关键词
phytoalexins; indoles; dioxane dibromide; spirocyclization; antitumor activity
The first syntheses of cruciferous indole phytoalexins (+/-)-1-methoxyspirobrassinin, (+/-)-1-methoxyspirobrassinol, (+/-)-1-methoxyspirobrassinol methyl ether as well as a new syntheses of phytoalexins (+/-)-spirobrassinin and cyclobrassinin were achieved by dioxane dibromide (DDB)-mediated spirocyclization of brassinin and its I-substituted derivatives. (C) 2002 Elsevier Science Ltd. All rights reserved.
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