期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 191, 期 1, 页码 29-33出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(02)00078-X
关键词
chiral 1,10-phenanthrolines; copper complex; allylic oxidation reaction; enantioselectivity
A number of chiral 1,10-phenanthrolines (phens) have been assessed in asymmetric Cu(I)-catalyzed allylic oxidation of cyclohexene. Very effective copper-phen catalysts are obtained only when these ligands bear at least a substituent close to the reactive site of the catalyst. Enantioselectivity up to 36% was obtained. (C) 2002 Elsevier Science B.V. All rights reserved.
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