期刊
ADVANCED MATERIALS
卷 15, 期 1, 页码 33-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200390003
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A substantial enhancement of thermal stability, volatility, and electron affinity, switching the semiconducting behavior from p- to n-type, is achieved by fluoroalkyl substitution of thiophene oligomers (see Figure). When this novel series is compared with the fluorine-free analogues, trends in molecular packing, optical absorption, HOMO-LUMO gap, and pi-pi interactions are found to be strikingly similar.
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