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Photoexcited crystallography of diplatinum complex by multiple-exposure IP method

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CHEMISTRY LETTERS
卷 32, 期 1, 页码 62-63

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CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.62

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Molecular distortion of a photoexcited diplatinuin(II) complex in a single crystal has been directly observed by accurate synchrotron radiation diffraction studies. Photoexcited crystallographic analysis has revealed that a small portion of [Pt-2(pop)(4)](4-) (pop = H2O5P22-) Complex shows the Pt-Pt bond shrinkage of 0.23 Angstrom under blue laser irradiation.

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