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Gas-occlusion properties of a novel compound: Mononuclear copper(II) terephthalate-pyridine

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CHEMISTRY LETTERS
卷 32, 期 1, 页码 34-35

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CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.34

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Mononuclear copper(II) terephthalate-pyridine, which has a regular one-dimensional structure, occludes large amounts of gases. The maximum amount of N-2 gas that can be occluded by mononuclear copper(II) terephthalate-pyridine is 1.1 mole per mole of copper(II) salt, indicating the presence of a large number of micropores. A porous structure, which is formed by hydrogen bonding and self-assembly of the linear copper(II) terephthalate-pyridine, was determined by X-ray crystallography.

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