期刊
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
卷 108, 期 B1, 页码 -出版社
AMER GEOPHYSICAL UNION
DOI: 10.1029/2001JB001663
关键词
high-pressure; silica; equations of state; Hugoniot; phase transitions
We present an isothermal equation of state for the high-pressure stishovite phase of SiO2 based on synchrotron X-ray diffraction at 300 K to 60 GPa. The inferred equation of state is the same for stishovite synthesized from pure SiO2 glass as from a natural, basalt glass that forms stishovite in association with other mineral phases, yielding a zero-pressure bulk modulus K-0T = 312.9(+/-3.4) GPa and pressure derivative K-0' = 4. 8(+/-0.2). Our measurements of stishovite at static, high pressures predict a shock-compressed (Hugoniot) state that is 2.4 (+/-1.6)% denser than observed for SiO2, suggesting that an amorphous phase, rather than stishovite, is produced under impact loading.
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