期刊
PHYSICAL REVIEW LETTERS
卷 90, 期 4, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.90.048304
关键词
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The phase behavior of poly-N-isopropylacrylamide (PNIPAM) nanoparticles dispersed in water is investigated using a thermodynamic perturbation theory combined with light-scattering and spectrometer measurements. It is shown how the volume transition of PNIPAM particles affects the interaction potential and determines a novel phase diagram that has not been observed in conventional colloids. Because both particle size and attractive potential depend on temperature, PNIPAM aqueous dispersion exhibits phase transitions at a fixed particle number density by either increasing or decreasing temperature.
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