期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2003, 期 3, 页码 488-491出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200390083
关键词
matrix isolation; photochemistry; isomerizations; silicon; density functional calculations
The reaction of silicon atoms with benzene in argon at 10 K has been studied. The addition to the aromatic pi-system of benzene occurs in a [1,4]-fashion. Upon irradiation the pi-adduct 7-silabicyclo[2.2.1]heptadien-7-ylidene (2) rearranges to the formal C-C insertion product 1-silacycloheptatrienylidene (3). The structural elucidation of the new species is based on comparison of the experimental observations with density functional calculations.
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