期刊
JOURNAL OF CHEMICAL PHYSICS
卷 118, 期 5, 页码 2357-2366出版社
AMER INST PHYSICS
DOI: 10.1063/1.1533735
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The Eley-Rideal reactions of H atoms with Cl adsorbed on Au(111) surfaces are examined. Electronic structure calculations based on density functional theory are used to construct a model potential energy surface. Both quantum and quasiclassical methods are used to compute reaction cross sections and product state distributions. Steering of the incident H atom towards the adsorbed Cl leads to relatively large reaction cross sections of 2-3 Angstrom(2). The product HCl in this strongly exothermic reaction has over an eV of energy in vibrational motion, and a bit less than one eV each in rotation and translation. (C) 2003 American Institute of Physics.
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