Structure-property relationship of castor oil based diol chain extended polyurethanes (PUs)

A series of 1,4-butane diol and 1,6-hexane diol based chain extended polyurethanes (PUs) have been prepared using castor oil with different diisocyanates such as methylene bis (phenyl isocyanate) (MDI), toluene-2,4-diisocyanate (TDI) and hexa methylene diisocyanate (HMDI) as crosslinkers. The prepared aliphatic diol based chain extended PU's have been characterised for physico-mechanical properties such as density, tensile strength, percentage elongation at break, tensile modulus and surface hardness; and optical properties like total transmittance and haze. The properties imparted by the chain extenders and diisocyanates on PUs have been explained on the basis of chemical structure. Effect of heat aging on mechanical properties of PUs have also studied. These changes have been interpreted quantitatively in terms of microcrystalline parameters computed using wide-angle X-ray scattering (WAXS) data. (C) 2003 Kluwer Academic Publishers.