期刊
SYNLETT
卷 -, 期 3, 页码 361-364出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2003-37117
关键词
coupling; sulfones; palladium; catalysis; arenesulfinates
The palladium-catalyzed coupling of arenesulfinate salts and aryl bromides or triflates provides a simple and extremely efficient route to unsymmetrical diaryl sulfones. The reaction was found to be strongly influenced by the presence of n-Bu4NCl. The ammonium salt tends to favor the formation of sulfones with neutral, electron-rich and slightly electron-poor aryl bromides or triflates and to hamper the reaction with electron-poor aryl bromides or triflates.
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