期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 125, 期 7, 页码 1821-1824出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja027658s
关键词
-
Treatment of nonstabilized beta-hydroxy phosphonic acid mono methyl esters with diisopropyl carbodiimide at ambient temperature leads to clean stereospecific elimination. The phosphonic acid mono alkyl esters are accessible by the selective partial saponification of dimethyl or diethyl alkyl phosphonates with NaOH or MgBr2. Isolated yields over both hydrolysis and elimination steps average 55-75%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据