期刊
ORGANIC LETTERS
卷 5, 期 4, 页码 587-590出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol027575g
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资金
- NIGMS NIH HHS [GM-29028] Funding Source: Medline
[GRAPHICS] The total synthesis of (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-5, a highly efficient union of the eastern and western fragments (-)-5 and 4, respectively, exploiting our 2-substituted indole synthesis, and a new protocol for the construction of ring C.
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