Spectrophotometric determination of molybdenum with Alizarin Red S in the presence of poly(sulfonylpiperidinylmethylene hydroxide)

The present work describes a selective and rapid method for the determination of molybdenum with Alizarin Red S (ARS) in the presence of a water soluble polymer, poly(sulfonylpiperidinylmethylene hydroxide) (PSPMH). The ARS modified by PSPMH reacts with molybdenum(VI) in the solutions of pH 3.4-4.0 to produce a red complex. The composition of the complex is 1:4:1 mol ratio of Mo(VI): ARS:PSPMH. The complex obeys Beer's law from 0.05 to 5.50 mug ml(-1) with an optimum range. The molar absorptivity is 2.1 x 10(4) l mol(-1) cm(-1) at 500 nm. The interference effects of the foreign cations have been examined and it has been determined that only Cu(II), Al(III) and Fe(III) have to be masked by EDTA and tungsten can be tolerated till 4-fold of molybdenum in case of masking by citrate. The method has been applied to the determination of geological samples without solvent extraction or separation steps. (C) 2002 Elsevier Science B.V. All rights reserved.