期刊
POLYMER
卷 44, 期 6, 页码 1927-1933出版社
ELSEVIER SCI LTD
DOI: 10.1016/S0032-3861(02)00940-0
关键词
tensile deformation; true stress-strain curve; homogeneous strain distribution
The mechanisms of tensile deformation in high density polyethylene/low density polyethylene (RDPE/LDPE) blends were studied by a video-controlled tensile set-up, combined with dynamic mechanical analysis and small angle X-ray scattering. When quenching from the melt to room temperature, HDPE forms well-organized spherulits with high crystallinity and rigid amorphous layers between lamellae, and LDPE forms irregular aggregates with low crystallinity and mobile amorphous layers between lamellae. A separate lamellar stack-like structure is formed in HDPE/LDPE blends during the quenching, The deformation is affected by both the crystal structure and the phase morphology. Because the semi-crystalline polymers are made up of two interpenetrating networks, one is built up by the entangled fluid part and the other by the crystallites, at low deformations the coupling and coarse slips of the crystalline blocks dominate the mechanical properties, which allows the system to maintain a homogeneous strain distribution in the sample. The assumption of a homogeneous strain distribution can now be further proved by the tensile deformation in HDPE/LDPE blends, which shows two-step processes, with HDPE crystallites being broken down first at imposed strain of 0.4 and then LDPE crystallites being broken later. at an imposed strain of 0.6. (C) 2003 Elsevier Science Ltd. All rights reserved.
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