期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2003, 期 6, 页码 963-966出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200390151
关键词
homogeneous catalysis; metathesis; olefins; ruthenium
The one-step synthesis of ruthenium carbene precatalyst 7 from inexpensive alpha-asarone [(E)-6] is described. This recyclable and easy to obtain complex can be used successfully in various types of metathesis (RCM, CM, enyne) as a cheaper and more potent substitute of the Hoveyda-type precatalyst 2b.
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