4.5 Article

A good bargain:: An inexpensive, air-stable ruthenium metathesis catalyst derived from α-asarone

期刊

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2003, 期 6, 页码 963-966

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200390151

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homogeneous catalysis; metathesis; olefins; ruthenium

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The one-step synthesis of ruthenium carbene precatalyst 7 from inexpensive alpha-asarone [(E)-6] is described. This recyclable and easy to obtain complex can be used successfully in various types of metathesis (RCM, CM, enyne) as a cheaper and more potent substitute of the Hoveyda-type precatalyst 2b.

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