期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 6, 期 3, 页码 244-248出版社
ELSEVIER
DOI: 10.1016/S1387-7003(02)00751-7
关键词
hydrothermal; open-framework; benzene-1,2,4-tricarboxylate; coordination polymer
A chiral 3-D open-framework coordination polymer [Co-3(mu(3)-OH)(mu(5)-btc)(mu(6)-Hbtc)(H2O)(3) . 6H(2)O]n was successfully obtained from the mixture of Co(CH3COO)(2) . 4H(2)O, H(3)btc (where H(3)btc = benzene- 1,2,4-tricarboxylic acid), NaOH and H2O under hydrothermal condition, which contains a novel and unprecedented coordination mode of btc (see Scheme 1). (C) 2002 Elsevier Science B.V. All rights reserved.
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