期刊
ASIAN JOURNAL OF CHEMISTRY
卷 26, 期 17, 页码 5703-5708出版社
ASIAN JOURNAL OF CHEMISTRY
DOI: 10.14233/ajchem.2014.18187
关键词
Polymer electrolyte; Waterborne polyurethane; Polydimethylsiloxane; Copolymerization; Ionic conductivity
类别
-
资金
- National Key Program for Basic Research of China [2009CB220100]
- National High-tech 863 Key Program [2011AA11A235]
- Basic Research Fund of Beijing Institute of Technology [31000-12211111]
New waterborne polyurethane polymer electrolytes containing poly(ethylene glycol) and polydimethylsiloxane (PDMS) in the soft segments were designed and synthesized. The structure and performance of the electrolytes were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, electrochemical impedance spectroscopy and linear sweep voltammetry. The membranes exhibited good electrochemical stability. The thermal stability of the polymer electrolytes increased with increased content of polydimethylsiloxane. The conductivity results indicated that the incorporation of polydimethylsiloxane up to a certain amount (17 wt %) increased the ionic conductivity, but further addition decreased the conductivity. Gel polymer electrolytes were obtained by immersing polymer membranes in 1 M LiTFSI/DMC+ EC (DMC: EC = 1: 1 by weight) for different durations. These electrolytes possessed good ionic conductivity, i.e., ca. 2.52 x 10(-3) S/cm with a swollen percentage of 130 wt % at room temperature.
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