期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 9, 期 6, 页码 1259-1262出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200390142
关键词
carbenes; heterogeneous catalysis; metathesis; ruthenium; synthetic methods
Grubbs' carbene complex [Cl-2(Cy3P)(2)Ru=CHPh] and its second-generation counterpart [Cl-2(Im)(CY3P)Ru=CHPh] have demonstrated remarkable efficiency metathesizing olefins. Furthermore, a growing number of newly discovered catalytic processes mediated by this complex broaden its synthetic utility beyond olefin metathesis. In addition, the ready availability of these stable ruthenium-based catalysts coupled with their tolerance toward a wide variety of common functional groups make Grubbs' catalysts very convenient synthetic tools. This paper presents recent advances in the non-metathetic behavior patterns of Grubbs' carbene.
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