期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 41, 期 3, 页码 313-321出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0926-3373(02)00169-8
关键词
TiO2 pillared clay; photocatalyst; endocrine disruptor; adsorption; hydrophobic interaction; photodegradation
TiO2 pillared clay was applied for the adsorption-photocatalytic degradation of the endocrine disruptors with various hydrophobicities (di-n-butyl phthalate, diethyl phthalate, dimethyl phthalate and bisphenol-A). The hydrothermal treatment developed the crystallinity of the TiO2 pillar and the size of the TiO2 crystallites, and enhanced the photocatalytic degradation rate. However, the hydrothermal treatment in hard condition made the specific photocatalytic activity decrease since the size of crystallites increased. The surface hydrophobicity of the pillared clay was not affected so much, but reduced slightly, by the hydrothermal treatment. Higher hydrophobic endocrine disruptor was more adsorbed and enriched on the TiO2 pillared clay. Enrichment of the reactant enhanced the rate of photocatalytic degradation on the pillared clay. (C) 2002 Elsevier Science B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据