期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 107, 期 12, 页码 2719-2724出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp026920g
关键词
-
A simple method is proposed to control the size of alkanethiol-protected Au nanoparticles by heat treatment in the solid state. The mean diameter of the An nanoparticles prepared by Brust's two-phase method (similar to1.5 nm) was evolved to 3.4-9.7 nm by heating to 150-250 degreesC in air. The uniform growth of nanoparticles was not observed when tetraoctylammonium bromide (TOAB), which was used as a phase-transfer agent during the preparation of An nanoparticles, was removed before the particle growth process. The crystal structures of Au nanoparticles and alkanethiol ligand structures on An nanoparticles were characterized before and after the heat treatment. The size-evolution mechanism was discussed on the basis of the thermodynamic model. The heat-treated An nanoparticles easily formed self-assembled 2D superlattices with hexagonal packing, where the alkanethiol protective agents with an all-trans conformation were estimated to interpenetrate each other.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据