期刊
SCIENCE
卷 299, 期 5615, 页码 2049-2052出版社
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.1082456
关键词
-
Although many volatile binary boron hydride compounds are known, binary aluminum hydride chemistry is limited to the polymeric (AlH3)(n) solid. The reaction of laser-ablated aluminum atoms and pure H-2 during codeposition at 3.5 kelvin, followed by ultraviolet irradiation and annealing to 6.5 kelvin, allows dinnerization of the intermediate AlH3 photolysis product to form Al2H6. The Al2H6 molecule is identified by seven new infrared absorptions that are accurately predicted by quantum chemical calculations for dibridged Al2H6, a molecule that is isostructural with diborane.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据