期刊
RUSSIAN CHEMICAL BULLETIN
卷 52, 期 4, 页码 781-794出版社
CONSULTANTS BUREAU
DOI: 10.1023/A:1024465718716
关键词
complexes; structure; platinum metals; NMR of donor atoms; H-1 NMR spectroscopy; C-13 NMR spectroscopy; N-14 NMR spectroscopy; O-17 NMR spectroscopy; F-19 NMR spectroscopy; P-31 NMR spectroscopy; Sn-119 NMR spectroscopy
Data on the NMR spectroscopy of C, N, O, Si, P, and Sn donor atoms of platinum metal complexes in solutions are surveyed. The chemical shift of a donor atom mainly depends on the ligand in the trans-position (due to the trans-effect). The chemical shift of a donor atom on a particular coordinate of the complex (coordinate shift, CSh) is an attribute of this coordinate and can be used to identify such a coordinate in platinum metal complexes and to determine the structures of complexes. Based on the known data, CSh diagrams were composed for H-1, C-13, N-14, O-17, F-19, P-31, and Sn-119. Examples of using the CShs for determining the structures of platinum metal complexes in solutions are presented.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据