期刊
CHEMOSPHERE
卷 51, 期 4, 页码 237-243出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0045-6535(02)00815-9
关键词
trichlorophenol; ozone; hydrogen peroxide; humic acid; dechlorination
The aqueous reactivity of 2,4,6-trichlorophenol (TCP) with ozone has been studied at laboratory-scale using a simple gas bubble/liquid contacting system. Degradation rate constants were measured directly and found to be 7.6 and 77.2 M-1 s(-1) at pH 2 and 7.5, respectively. At pH 7.5, 10 min of ozonation (equivalent to15 mM ozone consumption) achieved a 90% degradation of TCP, which corresponded to the release of approximately 2 mol Cl- per mol. TCP. The presence of hydrogen peroxide in solution did not significantly increase the TCP degradation but increased the overall dechlorination to 2.7 mol Cl- per mol TCP. The presence of humic acid (HA) in solution was found to enhance the degradation rate of TCP at low relative HA concentrations (<0.6 g/g HA:TCP), but to reduce the rate at higher HA concentrations. (C) 2003 Elsevier Science Ltd. All rights reserved.
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