Evaluation of the pozzolanic activity of fluid catalytic cracking catalyst residue (FC3R).: Thermogravimetric analysis studies on FC3R-Portland cement pastes

Spent fluid catalytic cracking catalyst (FOR) from a petrol refinery has shown a great pozzolanic activity in lime pastes as have been demonstrated in previous studies. Based on these results, the pozzolanic activity of the FOR in Portland cement pastes has been investigated. This evaluation has been carried out by means of thermogravimetry (TG) of cured FC3R-Portland cement pastes. The influence of water/ binder ratio and the replacement percentage of FC3R on the pozzolanic reaction were investigated. Due to the chemical composition of FC3R that is similar to metakaolin (MK), and knowing that MK has a high pozzolanic activity, the latter was used as a material of comparison in the study of the water/binder ratio influence. The scope of this study is the determination of pozzolanic activity of FOR when incorporated to Portland cement, and the evaluation on amount and nature of pozzolanic products. FOR has shown a similar reactivity to MK, yielding similar pozzolanic products: CSH, CAH and CASH. The optimum replacing percentage in Portland cement pastes was in the 15-20% range. (C) 2002 Elsevier Science Ltd. All rights reserved.