期刊
TRANSITION METAL CHEMISTRY
卷 28, 期 3, 页码 331-335出版社
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1022987521974
关键词
-
M(CO)(6) (M = Mo and W) reacts with 2,2'-biquinoline (biq) to yield tetracarbonyl derivatives M(CO)(4)(biq). Crystals suitable for X-ray structure determination of W(CO)(4)(biq) were isolated from benzene solution. The u.v.-vis. spectra of the complexes exhibited visible transitions due to metal-to-ligand charge-transfers. Electrochemical investigation of the complexes showed some irreversible, reversible and quasi-reversible redox reactions due to tautomeric interconversions through electron transfer. The thermal properties of the complexes were also investigated using the thermogravimetric technique.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据