期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2003, 期 7, 页码 1172-1183出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200390171
关键词
polyesters; agarofuran; natural products; terpenoids; oxidation
This paper describes the synthesis of polyhydroxylated decalinic systems through oxidative furan ring opening of 3-(2'-furyl)-2-methoxycarbonylcyclohexadione-4-monoethylene ketal 12 using dimethyl dioxirane (DMDO). The functionalisation of the decalinic product 5, aimed at the synthesis of antifeedant agarofuran sesquiterpenes according to our previously reported strategy, is demonstrated to occur with good stereochemical control of the introduced oxygenated functions, using as a key step an original allylic oxidation by DMDO. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据