期刊
ORGANIC LETTERS
卷 5, 期 7, 页码 1143-1146出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0300219
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资金
- NIGMS NIH HHS [R01 GM65149-01] Funding Source: Medline
[GRAPHIC] Formal heterolytic activation of elemental hydrogen under Rh catalysis enables the reductive generation of enolates from enones under hydrogenation conditions. Enolates generated in this fashion participate in catalytic C-C bond formation via carbonyl addition to aldehyde and, as demonstrated in this account, ketone partners. Notably, the use of appendant dione partners enables diastereoselective formation of cycloaidol products possessing 3-stereogenic centers, including 2-contiguous quaternary centers.
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