期刊
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
卷 13, 期 7, 页码 1377-1379出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0960-894X(03)00097-0
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Upon photolysis, diiron complexes 1,4- and l,3-Fp(2)C(6)H(4) (1 and 2) linearize plasmid DNA at ratios as low as 1.5 and 3.0 molecules/bp DNA, respectively. Additionally, single-strand cleavage was observed at ratios higher than 0.05 and 0.19 molecules/ bp DNA for 1 and 2, respectively. Radical scavenging studies and metal radical control experiments implicate carbon-centered radicals as participants in the cleavage pathway. (C) 2003 Elsevier Science Ltd. All rights reserved.
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